Synthetic agricultural product

ABSTRACT

The disclosure relates generally to a synthetic agricultural product and methods and systems for producing a synthetic agricultural product or composition. The method of producing a synthetic agricultural product may comprise providing an effective amount of fertilizer and/or other agricultural product sufficient to effectuate a response in a plant, an effective amount of a mineral substance having a high cation exchange capacity, and an effective amount of water sufficient to effectuate a desired result in a plant. The fertilizer and/or other agricultural product and mineral substance may be added into the effective amount of water, thereby creating the synthetic agricultural product. Known ions, such as fertilizer ions, and native ions in the native mineral substance may be exchanged to produce a synthetic agricultural product.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of U.S. Provisional Application No.62/220,603, filed Sep. 18, 2015, which is hereby incorporated byreference herein in its entirety, including but not limited to thoseportions that specifically appear hereinafter, the incorporation byreference being made with the following exception: In the event that anyportion of the above-referenced provisional application is inconsistentwith this application, this application supersedes said above-referencedprovisional application.

TECHNICAL FIELD

The disclosure relates generally to methods, systems and compositionsrelating to agricultural products, and more particularly, but notnecessarily entirely, to a liquid synthetic agricultural product orcomposition and methods and systems for producing the liquid syntheticagricultural product or composition.

BACKGROUND

Current fertilization systems often struggle to deliver nutrition orother agricultural product directly to the plant cell. Accordingly, itis common in the farming or other plant growing industries to providemuch more of the fertilizer composition and/or other agriculturalproducts than is actually needed or used by the plant. Such practicesmay have negative impacts on the environment and ultimately increase thecost of farming and plants that are provided to the marketplace.

The features and advantages of the disclosure will be set forth in thedescription which follows, and in part will be apparent from thedescription, or may be learned by the practice of the disclosure withoutundue experimentation. The features and advantages of the disclosure maybe realized and obtained by use of the instruments and combinationsparticularly pointed out in the appended claims, if any.

BRIEF DESCRIPTION OF THE DRAWINGS

Non-limiting and non-exhaustive implementations of the presentdisclosure are described with reference to the following figures,wherein like reference numerals refer to like parts throughout thevarious views unless otherwise specified. Advantages of the presentdisclosure will become better understood with regard to the followingdescription and accompanying drawings where:

FIG. 1A is a flow chart of an implementation of a method of producing aliquid fertilizer and/or agricultural product in accordance with theteachings and principles of the disclosure;

FIG. 1B is a flow chart of an implementation of a method of producing aliquid fertilizer and/or agricultural product in accordance with theteachings and principles of the disclosure;

FIG. 1C is a flow chart of an implementation of a method of producing aliquid fertilizer and/or agricultural product in accordance with theteachings and principles of the disclosure;

FIG. 2 is flow chart of an implementation of a method of producing aliquid fertilizer and/or agricultural product in accordance with theteachings and principles of the disclosure;

FIG. 3 is a drawing of a synthetic agricultural product made inaccordance with the teachings and principles of the disclosure;

FIG. 4 illustrates an example of a synthetic mineral substance inaccordance with the teachings and principles of the disclosure;

FIG. 5 is a diagram illustrating an ion exchange process in accordancewith the teachings and principles of the disclosure;

FIG. 6 is a diagram illustrating an ion exchange process in accordancewith the teachings and principles of the disclosure; and

FIG. 7 illustrates an example of a synthetic mineral substancecomprising agricultural product within exchange sites of the mineralsubstance in accordance with the teachings and principles of thedisclosure.

DETAILED DESCRIPTION OF THE DISCLOSURE

For the purposes of promoting an understanding of the principles inaccordance with the disclosure, reference will now be made to theimplementations and embodiments illustrated in the drawings and specificlanguage will be used to describe the same. It will nevertheless beunderstood that no limitation of the scope of the disclosure is therebyintended. Any alterations and further modifications of the inventivefeatures illustrated herein, and any additional applications of theprinciples of the disclosure as illustrated herein, which would normallyoccur to one skilled in the relevant art and having possession of thisdisclosure, are to be considered within the scope of the disclosureclaimed.

Before the agricultural products, compositions and methods forsuspending fertilizer and/or agricultural products in a solution aredisclosed and described, it is to be understood that this disclosure isnot limited to the particular configurations, process steps, ingredientsand materials disclosed herein as such configurations, process steps,ingredients, and materials may vary somewhat. It is also to beunderstood that the terminology employed herein is used for the purposeof describing particular embodiments and implementations only and is notintended to be limiting since the scope of the disclosure will belimited only by the appended claims, if any, and equivalents thereof.

The publications and other reference materials referred to herein todescribe the background of the disclosure, and to provide additionaldetail regarding its practice, are hereby incorporated by referenceherein in their entireties, with the following exception: In the eventthat any portion of said reference materials is inconsistent with thisapplication, this application supersedes said reference materials. Thereference materials discussed herein are provided solely for theirdisclosure prior to the filing date of this application. Nothing hereinis to be construed as a suggestion or admission that the inventors arenot entitled to antedate such disclosure by virtue of prior disclosure,or to distinguish the disclosure from the subject matter disclosed inthe reference materials.

In describing and claiming the subject matter of the disclosure, thefollowing terminology will be used in accordance with the definitionsset out below.

It must be noted that, as used in this specification and the appendedclaims, if any, the singular forms “a,” “an,” and “the” include pluralreferents unless the context clearly dictates otherwise.

As used herein, the terms “comprising,” “including,” “containing,”“characterized by,” and grammatical equivalents thereof are inclusive oropen-ended terms that do not exclude additional, unrecited elements ormethod steps.

As used herein, the phrase “consisting of” and grammatical equivalentsthereof exclude any element, step, or ingredient not specified in theclaim.

As used herein, the phrase “consisting essentially of” and grammaticalequivalents thereof limit the scope of a claim to the specifiedmaterials or steps and those that do not materially affect the basic andnovel characteristic or characteristics of the claimed disclosure.

As used herein, the term “ultrapure water” is intended to mean waterthat has been purified such that it measures 18.3 mega ohms ofresistance or less, and may include water having a designation to thoseskilled in the art of “ultrapure water.” Pure water is intended todenote water that is relatively reactive (when compared to water havingcontaminants therein) with its surroundings due primarily to thepolarized nature of water molecules. For example: it should be notedthat, water, a tiny combination of three nuclei and ten electronspossesses special properties that make it unique among the more than 15million chemical species we are presently aware of and essential to alllife. A water molecule is electrically neutral, but the arrangement ofthe hydrogen atoms and the oxygen atom is such that a chargedisplacement is created thus constituting an electric dipole, or polarmolecule, with one end (the end with the hydrogen atom) being positiveand the other end (the end with the oxygen atom) being negative.Because, opposite charges attract, the negative end of one watermolecule will tend to orient itself in a fashion that will bring itclose to the positive end of another molecule that is nearby. Generallyspeaking, this dipole-dipole attraction is less than that of a normalchemical bond, and is dynamic in nature. Further, this attraction causescomplex structures that are temporary in nature and thus alwayschanging. The various structures can be influenced by other elements(contaminants) that can provide electrical balance for these structures,thereby stabilizing the structures and making a body of water lessreactive.

Water is a unique compound that has many different chemical and physicalproperties. For example, water molecules may include any or all of thefollowing bonding types. In water, a strong hydrogen bond is presentwith the OH covalent bond within the water molecule. A weak hydrogenbond is the bond between two water molecules. This weak hydrogen bond isalso responsible for water bonding with ammonia, for example (thusammonia's remarkably high solubility in water). Water also includesionic attraction due to their positive and negative ions. By way ofexample, sodium ions and chlorine ions have an ionic attraction, whichwill form an ionic bond creating sodium chloride. Water also experiencespermanent dipole moments; H2O, NH3, and PC13 are examples of moleculeswith a permanent dipole moment. Water may also include ion-dipoleinteractions. Sodium ions in water will create an ion-dipole interactionwhere the dipole will orient its' negative side towards the sodium (apositive ion). Chlorine ions conversely will create an ion-dipoleinteraction where the dipole will orient its' positive side towards thechlorine (a negative ion). Water may also experience dipole-dipoleinteractions. Dipoles will orient themselves with their negativelycharged side towards the other's positively charged side. Water may alsoexperience ion-induced dipole interactions. Nearby ions can distortelectron clouds (even in dipoles) temporarily changing their dipolemoments. This effect is particularly strong in larger ions such asSO22—this action can play a dominant role in compound formation. Watermay also experience dipole-induced dipole interactions. Hydrocarbons,which are non-polar in nature, may create an example of a dipole (inthis case water) creating a hydrate compound as the water dipole createsa temporary dipole out of the non-polar species (the hydrocarbons).Water may also experience dispersion (London force) interactions. Thesedipole independent forces are evidenced when we consider that nitrogenas N2 may be condensed to liquids or solids.

It will be understood that ultrapure water contains virtually noinorganic matter, such as cations, anions, solids, nor does it containorganic matter, such as carbon based material. The ASTM definition forultrapure water, as it relates to resistivity, is shown below and thisdisclosure includes through type E-4:

Type Type Type Type Type Type Type E- E- E- E- E- E- E- Parameter 1 1.11.2^(B) 1.3^(B) 2 3 4 Resistivity, 18.3 18.2 18.2 18.2 16.5 12 0.5 25°C.Ultrapure water may be established using any known protocol, but oneexemplary multi-stage process begins with: carbon filtration, softening,reverse osmosis, deionization, exposure to ultraviolet light orradiation, and sub-micron filtration.

As used herein, “nano particle” or “nano particle size” includes anaverage compound or element size having a diameter in any one dimensionthat is 100 nanometers or less. As used herein, “submicron particle” or“submicron particle size” includes an average compound or element sizehaving a diameter in any one dimension that is within a range of about101 nanometers to about 1000 nanometers.

As used herein, “effective amount” means an amount of a component of afertilizer, an agricultural product, or other compound or elementsufficient to provide nutrition to a plant, or sufficient to effectuatethe desired response and performance, including killing a plant orundesirable organism, at a reasonable benefit/risk ratio attending anyagricultural product, compound and/or composition. For example, aneffective amount of a fertilizer compound is an amount sufficient topromote the optimal or desired maturation of plants. An effective amountof a phyllosilicate or tectosilicate or a mineral substance having ahigh ion exchange capacity is an amount sufficient to deliver aneffective amount of fertilizer or other agricultural product throughexchange of native ions on the mineral particles with knownions/molecules of an agricultural product such as fertilizer. Further,the effective amount of the phyllosilicate or tectosilicate or mineralsubstance must be sufficient to hold and deliver enough known ions andmolecules in an agricultural product to result in promoting the optimalor desired maturation of plants. In an implementation, depending uponthe desired ion of an agricultural product to be delivered to the plantcell, the amount of ions may be more than two orders of magnitude and upto, and including, seven orders of magnitude more than available ionexchange sites within the phyllosilicate or tectosilicate mineralsubstance. It will be appreciated that more or less known ions, such asfertilizer or other agricultural product, may be present withoutdeparting from the scope of the disclosure.

In order to determine the quantity of phyllosilicate or tectosilicatemineral substance, the amount of agricultural product desired in theplant is calculated first. The amount of phyllosilicate or tectosilicateor mineral substance is then determined based on the number of knownions of the agricultural product and the number of exchange sites on themineral substance. As native ions are removed from the mineral substance(cation exchange), known ions in the solution can take the place of theremoved native ions and the known ions in the solution may then bedisplaced in or otherwise delivered inside the plant. It will beappreciated that sometimes the native ions “on” the phyllosilicate ortectosilicate or mineral substance are tightly bound and can only beremoved with a concentrated solution of known ions. In such cases, it isnecessary to create a solution with at least two orders and up to sevenorders of magnitude of known ions more than the available exchange sitesin the mineral substance.

Referring now to FIG. 1A, there is illustrated a method of producing aliquid product. In an implementation, the method 100 may comprise at 105providing an effective amount of an agricultural product sufficient toeffectuate a desired result in a plant comprising known ions, aneffective amount of a mineral substance having a high cation exchangecapacity, and an effective amount of water sufficient to effectuate adesired result in a plant and maintain the effective amount of theagricultural product and the effective amount of the mineral substancein suspension and solution. Additionally, at 115, the method 100 maycomprise creating or forming a solution by adding the effective amountof the agricultural product and the effective amount of the mineralsubstance into the effective amount of water. At 125, the method 100 mayfurther comprise exchanging native ions in the mineral substance withthe known ions in the agricultural product by adding energy into thesolution to thereby raise an energy level of the solution to produce asynthetic mineral substance and a liquid product.

As used herein, the term “synthetic” includes “wholly synthetic”compounds, solutions, and substances and “partially synthetic”compounds, solutions, and substances. It will be appreciated that awholly synthetic compound, solution or substance is entirely generatedor synthesized in a laboratory, whereas a partially synthetic compound,solution or substance is chemically altered from its natural or nativestate. By way of example, a wholly synthetic mineral substance may be acrystalline structure that is generated or synthesized in a laboratorysetting from non-crystalline molecules and ions. By way of furtherexample, a partially synthetic mineral substance may be a crystallinestructure that is a native mineral that has been chemically altered in alaboratory. It will be appreciated that the laboratory may be a mobilelaboratory or a stationary factory or laboratory without departing fromthe scope of the disclosure.

Referring now to FIGS. 1B and 1C, there are illustrated methods ofproducing a liquid product, such as a liquid fertilizer and/or liquidagricultural product. In an implementation, the method 100 may compriseproviding an effective amount of a fertilizer and/or an agriculturalproduct sufficient to effectuate a response in a plant at 110. It willbe appreciated that the fertilizer and/or agricultural product type usedmay be in a liquid or solid form, such as dry particles or dry matterthat can be dissolved or suspended in water to form a solution orsuspension without departing from the scope of the disclosure. It willfurther be appreciated that any fertilizer and/or agricultural producttype, form, substance, compound or formulation may be utilized hereinwithout departing from the scope of the disclosure.

As used herein the phrase “agricultural products” refers broadly tomolecules, ions, compounds, solutions, and substances used to protectplants, such as pesticides, molecules, ions, compounds, solutions, andsubstances used to kill plants, such as herbicides, and molecules, ions,compounds, solutions, and substances used as plant growth regulators,such as those used to promote plant health, fruiting, growth, or thoseused to slow plant growth.

It will be understood that matching fertilizer and/or agriculturalproduct type and application rates to satisfy a plant's need is anessential component of optimizing plant production. However, differentplants in different soil environments, each having different soil typesand pHs and other environmental factors, will require varying rates ofthe major fertilizer nutrients, which are nitrogen (N), phosphate(P2O5), and potassium (potash, K2O). Plants also require the secondarynutrients, Sulphur (S), Calcium (Ca), and Magnesium (Mg), though inlesser quantities than the primary nutrients. Micronutrients are alsoconsidered essential though they are needed in still lesser quantities.Micronutrients include Chlorine (Cl), Manganese (Mn), Iron (Fe), Zinc(Zn), Copper (Cu), Molybdenum (Mo), and Nickel (Ni). Another elementthat is not considered essential, but is beneficial is Silicon (Si).Thus, due to variations in soil types, soil test nutrient levels, andnutrient ranges of different plants, different fertilizers, agriculturalproducts, and application rates may be required. Still further, themethods, compositions and agricultural products disclosed herein mayfurther affect the application rates, such that less fertilizer and/oragricultural product may be used to effectuate a response in or deliverythe desired result to a plant. In any case, to optimize plantproduction, a plant's need for nitrogen, phosphate, and potassium(sometimes abbreviated to N—P—K) nutrients along with the otheressential and beneficial nutrients must be met without over application.Thus, it will be appreciated that the disclosure may utilize any ofthese nutrients in any number of possible blends of fertilizer and/oragricultural product types to give the correct N—P—K and other nutrientratio for a given plant or plant. All of these essential and beneficialnutrients are typically in ionic form and can be exchanged with nativeions on a mineral substance. It should also be understood that ions andmolecules listed above along with other elements, ions, and moleculesmay be used to kill or limit growth in plant material or other organismssuch as insects, bacteria, fungi, viruses and other organisms byaltering the dosage such that it is toxic to those organisms. Forexample, Manganese levels of 25 to 200 ppm in citrus leaf tissues areconsidered adequate while levels above 1000 ppm may result in toxicity.In an implementation, the form of the fertilizer is a liquid fertilizeror combination of fertilizer and other beneficial molecules that promoteplant health and growth in a liquid form. It will be understood that inan embodiment the effective amount of liquid fertilizer may fall withina range of about 0.10 gallons to about 250 gallons per 250 gallons offinished liquid product without departing from the scope of thedisclosure. In an embodiment, for dry, water soluble products, the dryproduct may fall within a range of about 0.01 pounds to 1000 pounds per250 gallons of finished liquid product.

In an implementation, the form of the fertilizer and/or agriculturalproduct is a solid or dry fertilizer and/or agricultural product, or acombination of fertilizer, agricultural products, and/or otherbeneficial molecules that promote plant health and growth in a solid ordry form.

It will be appreciated that ion exchange (cation exchange or anionexchange) is a chemical process where ions are exchanged between twoelectrolytes or between an electrolyte solution and a complex. Thisprocess includes both cations (ions with a positive charge) and anions(ions with a negative charge). Ion exchangers (complexes) can includesynthetic gel polymers or natural substances. It will be appreciatedthat the mineral substance of the disclosure is the complex. Ionexchange on a complex occurs when preexisting ions on a complex arereleased in exchange for the binding of ions that have a higher affinityfor the complex. This process can be reversed by introducing a saturatedsolution of the lower affinity ions to the complex.

In an implementation, anions may be selectively removed from water byion exchange because different anions have different affinities, such asshown in this equation form: SO−−>NO3−−>, Cl−>, HCO3−>, OH−>, F−>. Forcations the affinity hierarchy is: (Pb++>, Ca++>, Mg++>, Na+>, Li+>,H+).

Continuing to refer to FIGS. 1B and 1C, in an implementation, the method100, at 120, may comprise providing an effective amount of a mineralsubstance that comprises a high cation exchange capacity. Cationexchange capacity may be determined by calculating a value that is anestimate of a substance's ability to attract, retain, and exchangecation elements. Cation exchange capacity is reported inmilliequivalents (meq) per 100 grams of a substance, which may be a soilsubstance, mineral substance, or other inorganic matter (meq/100 g). Ameq is the number of ions that total a specific quantity of electricalcharges. For example, a meq of potassium (K⁺) ions is approximately6×10²⁰ positive charges; whereas with calcium a meq of Calcium (Ca⁺⁺) isalso 6×10²⁰ positive charges, but only 3×10²⁰ ions because each calciumion has two positive charges. Although the minerals discussed here havehigh cation exchange capacity values, they do have a level of anionexchange capacity as well and the anion exchange can be utilized in thesame way as the cation exchange. The number of cations supplied by thefertilizer and/or agricultural product source should outnumber thenumber of cations occurring naturally on the mineral substance, suchthat the probability for the native ion being exchanged for a fertilizerand/or agricultural product cation is high and the probability of theoriginal cation being reintroduced onto the mineral substance isextremely low. Since most fertilizers and/or agricultural productsapplied in an agricultural or horticultural setting are often a mixtureof two or more primary, secondary, and micro nutrients, and that thecombinations are many and varied, it is difficult to describe all of thepossibilities, but the ions (both positive and negative) supplied by thefertilizer and/or agricultural product may be at least two orders andmay be equal to or up to seven orders of magnitude more abundant thanthe ions available for exchange (both positive and negative) nativelyoccurring on the mineral substance. Exception to this rule may be whenthe known ions in the fertilizer and/or agricultural product suppliedhave a single charge (especially positive ions) and have an extremelyhigh affinity for the soil particle—in other words, once the known ionsin the fertilizer and/or agricultural product are exchanged with thenative mineral ions the negatively (for example) charged soil particleonce ionically bound to the fertilizer and/or agricultural productcation (for example) would represent an extremely low energy state suchthat exchange is extremely unlikely.

It will be understood that cations held on the soil substance, mineralsubstance and inorganic matter particles in soil substances and mineralsubstances can be replaced by other cations. Thus, the ions in thesesoil substances, mineral substances, and inorganic matter areexchangeable. By way of example, iron can be replaced or exchanged bycations, such as calcium or potassium, and vice-versa. The total numberof cations a soil substance, a mineral substance or other organic matteror substance can hold—or its total negative charge—is the cationexchange capacity. The higher the cation exchange capacity, the higherthe negative charge and the more cations that can be held. High cationexchange capacity may be defined as 12 meq up to 600 meq.

It will be appreciated that the mineral substance may be in theconsolidated or aggregate form. In an implementation, the mineralsubstance is a zeolite of the zeolite group in the tectosilicate familyand can be naturally occurring or synthetically derived. Zeolites arecrystalline, hydrated aluminosilicates that contain alkali andalkaline-earth metals. Their crystal framework is based upon athree-dimensional network of SiO4 tetrahedra with all four oxygensshared by an adjacent tetrahedral. The alkali and alkaline earth cationsare loosely bound within this structure (by ionic bonding) and can beexchanged by other cations or molecular water. Most zeolites can bedehydrated and rehydrated without any change in volume. The importantphysical and chemical properties of zeolites are: high degree ofhydration, low density and large void volume when dehydrated, cationexchange properties, uniform molecular-sized channels in the dehydratedcrystals, ability to adsorb gases and vapors, and catalytic properties.

It will be appreciated that molecular sieves are materials that canselectively adsorb molecules on the basis of their size, shape, orelectrical charge. Commercial applications of zeolites are based on thefollowing properties: molecular sieving, ion exchange, adsorption, andcatalysis. Most zeolites are molecular sieves, but not all molecularsieves are zeolites. Activated carbon, activated clays, aluminum oxide,and silica gels are also molecular sieves. Activated synthetic andnatural zeolite molecular sieve products, however, have displaced manyof these substances because of their selectivity.

It will be appreciated that the basic structure of zeolites comprise(AlSi)O4 tetrahedra, wherein each oxygen atom is shared by twotetrahedra: thus, the atomic ration O:(Si+Al) is 2. The net negativecharge of the structure is balanced by exchangeable cations, which areloosely held within the central cavities by weak ionic bonding andsurrounded by water molecules. The cavities form a continuous network ofchannels that give this mineral the capabilities to adsorb water andother ionic solutions readily. The zeolite may comprise a hydratedsodium calcium aluminosilicate. Further, the mineral substance may bemade up of frameworks of AlO4 and SiO4 tetrahedra, which have largeinterconnecting spaces known as channels. Channels are filled with waterthat can be removed through heating without affecting thealuminosilicate structures.

It will be appreciated that the dimensions and orientation void spacesand the interconnected channels in dehydrated zeolites are importantdetermining the physical and chemical properties (see Figure of zeolitestructure). The three types of channel systems identified, are aone-dimensional system, a two-dimensional system, and two varieties ofthree-dimensional, intersecting systems. It will be appreciated thatonce there has been an exchange of known ions (such as ions commonlyfound in fertilizers and/or agricultural products) with the native orunknown ions at the exchange sites of the mineral substance, a vortex,high-pressure, or a high pressure cyclonic mixing action may be used tofill the channels or voids in the mineral substance with known ions,such as fertilizers and/or agricultural products or other nutrients, tocreate a mineral substance with known ions exchanged at the exchangesites as well as filling, at least in part, the channels of the mineralsubstance through diffusion. Since the preexisting ions in the nativezeolite are part of the native chemical structure, exchanging those ionswith new known ions results in a new and synthetic chemically alteredformula that describes the makeup of the zeolite, and as such isconsidered partially synthetic. It will be understood that in somemineral substances, such as clay, there may not be any channels or voidswhere additional ion exchange can take place, but instead there may onlybe exchange sites. Conversely, in other mineral substances, such aszeolite, there may be both exchange sites and channels or voids whereadditional ion exchange can take place between the native ions in themineral substance and the known ions in the fertilizer and/oragricultural product and/or other nutrient.

It will be appreciated that the character of the water in hydratedzeolite crystals varies, because it can include molecular clustering ordirect bonding between the cations and the framework oxygen molecules.The inter-crystalline volume that may be occupied by water constitutesup to 50% of the volume of the crystal. The adsorption capacity of azeolite is generally related to the free space or pore volume asdetermined by the quantity of contained water when fully hydrated at astandard temperature and humidity. Adsorption and ion-exchangecapacities in both hydrated and dehydrated zeolites are related to thecharacteristics of the channel openings. The apertures are bounded byoxygen atoms of the connected tetrahedral. The limiting size of theaperture is governed by the size of the rings, which contain 6, 8, 10,or 12 oxygen atoms.

It will be appreciated that the chemical properties of zeolites make useof one or more of their chemical properties, which include adsorption,cation exchange, and dehydration or rehydration. These properties arefunctions of the specific crystal structure of each mineral, itsframework, and its cationic composition.

It will be appreciated that crystalline zeolites are unique adsorbentmaterials. The large central cavities and entry channels (see Figure ofgeneralized zeolite structure) of the zeolite are filled with watermolecules that form hydration spheres around the exchangeable cations.If the water is removed, molecules having cross-sectional diameterssmall enough for them to pass through the entry channels are readilyadsorbed in the channels and central cavities and can be held thereuntil they are removed via diffusion. Molecules too large to passthrough the entry channels are excluded, which result in the molecularsieving property of most zeolites.

It will be appreciated that exchangeable cations of a zeolite areloosely bonded to the tetrahedral frame work and can be easily exchangedand removed by washing with a strong solution of another cation. Themeq/100 g or some zeolite minerals is between 200 meq/100 g and 500meg/100 g. Crystalline zeolites are very effective ion exchangers. Theion-exchange capacity is basically a function of the degree ofsubstitution of aluminum for silicon in the framework structure. Thegreater the substitution, the greater the charge deficiency, and thegreater the number of alkali or alkaline earth cations required forelectrical neutrality. Cation exchange behavior also depends on otherfactors, including: the concentration of the specific cation in thesolution; the temperature; the nature of the cation species (e.g., size,charge); and the structural characteristics of the particular zeolite.Cations can be trapped in structural positions that are relativelyinaccessible, thereby reducing the effective ion-exchange capacity.Cation sieving may also take place if the cation in solution is toolarge to pass through the entry ports into the central cavities. Unlikemost non-crystalline ion exchangers, the framework of a zeolite definesits selectivity toward competing ions, and different structures offerdifferent sites for the same cation. The hydration strength of some ionsprevents their close approach to the seat of charge within theframework. In many zeolites, ions having low field strength are moretightly held and are more selectively taken up from solutions than theother ions.

It will be appreciated that zeolites exhibit no major changes duringdehydration; they do exhibit continuous weight loss as a function oftemperature and will rehydrate. If the temperature required for completedehydration is exceeded, the zeolite structure collapses and rehydrationcannot occur. Most natural zeolites are thermally stable from 250° C. to400° C. (482° F. to 752° F.). Zeolites with higher silica contents, suchas mordenite and clinoptiloloite, collapse at temperatures greater than650° C. (1,202° F.).

It will be appreciated that clay minerals form flat hexagonal sheetssimilar to the mica group. Clay minerals may be hydrous aluminumphyllosilicates, sometimes with variable amounts of iron, magnesium,alkali metals, alkaline earths, and other cations. Clay minerals arecommon in fine-grained sedimentary rocks such as shale, mudstone, andsiltstone and in fine-grained metamorphic slate and phyllite. Clayminerals are usually (but not necessarily) ultrafine-grained (normallyconsidered to be less than 2 micrometers in size on standard particlesize classifications) and so may require special analytical techniquesfor their identification and study. These include x-ray diffraction,electron diffraction methods, various spectroscopic methods such asMössbauer spectroscopy, infrared spectroscopy, Raman spectroscopy, andSEM-EDS or automated mineralogy processes. These methods can beaugmented by polarized light microscopy, a traditional techniqueestablishing fundamental occurrences or petrologic relationships.

Clay minerals may be classified as 1:1 or 2:1, because they are built oftetrahedral silicate sheets and octahedral hydroxide sheets. A 1:1 claywould consist of one tetrahedral sheet and one octahedral sheet, andexamples would be kaolinite and serpentine. A 2:1 clay would consist ofan octahedral sheet sandwiched between two tetrahedral sheets, andexamples are talc, vermiculite and montmorillonite.

Clay minerals may include the following groups. 1) The Kaolin groupincludes the minerals kaolinite, dickite, halloysite, and nacrite(polymorphs of Al2Si2O5(OH)4). Some sources include thekaolinite-serpentine group due to structural similarities. 2) TheSmectite group includes dioctahedral smectites, such as montmorilloniteand nontronite, and trioctahedral smectites, for example saponite. 3)The Illite group includes the clay-micas. Illite is the only commonmineral. 4) The Chlorite group includes a wide variety of similarminerals with considerable chemical variation. Other 2:1 clay typesexist such as, for example, sepiolite or attapulgite, are clays withlong water channels internal to their structure.

It will be appreciated that mixed layer clay variations exist for mostof the above groups. Ordering is described as random or regularordering, and is further described by the range or reach. Such orderdescriptions may include an R1 ordered illite-smectite, for example.This clay type would be ordered in an ISISIS fashion. R0, on the otherhand, may include or describe random ordering. Other advanced orderingtypes may also be found, such as R3, etc. Mixed layer clay minerals,which are perfect R1 types often get their own names. For example, R1ordered chlorite-smectite is known as corrensite, and R1 illite-smectiteis known as rectorite.

In an implementation, the mineral substance may comprise one or more ofalumina silicate, silicate, aluminum, sodium aluminosilicate or othertuff material. In an implementation, the mineral substance comprises oneor more of montmorillonite, illite, kaolinite, smectite, zeolite,hydrated sodium calcium aluminosilicate (HSCAS), and vermiculite. In animplementation, the mineral substance comprises smectite. In animplementation, the mineral substance comprises zeolite. In animplementation, the zeolite mineral substance is a carrier of nutrientsand other small organic and inorganic molecules via ion exchange andadsorption inside the channels (formed by the crystalline structure).Zeolite channels may carry ions and small molecules used to protectplants, kill plants, or used as plant growth regulators, such as thoseused to promote plant health, fruiting, growth, or those used to slowplant growth for use by a cell.

In an implementation, the mineral substance having a high cationexchange capacity has an equivalents in a range of about 12Milliequivalents/100 g to about 600 Milliequivalents/100 g.

The concentration of mineral particles in solution is within a range of1×10⁻⁸ mg/ml to 1×10⁴ mg/ml. The concentration of agricultural productions ranges from 0.01 mg/ml to saturation point.

Continuing to refer to FIGS. 1B and 1C, it will be appreciated that themethod 100 may further comprise providing an effective amount of watersufficient to effectuate a desired result in a plant and maintain theeffective amount of a fertilizer and/or agricultural product and theeffective amount of the mineral substance in suspension and solution at130. The effective amount of water may fall within a range of about 0.1gallon to about 6000 gallons.

The method 100 may further comprise bathing an effective amount of themineral substance in ultrapure water at 140. In an implementation of themethod, the step of bathing the effective amount of the mineralsubstance in ultrapure water comprises bathing the mineral substance forat least 24 hours. The process of bathing the mineral substance mayassist in preparing the mineral substance by removing native ions andmolecules held by water in the channels through diffusion. Ultrapurewater may be used to make the ions in the soil substance, mineralsubstance, or other organic material readily available for exchange.Thus, when the soil substance, mineral substance, or other organicmaterial is bathed in ultrapure water, the ions in the mineral substanceare exposed or otherwise made readily available for ion exchange withanother known substance. Thus, in an implementation, the method andsystem of the disclosure may comprise exchanging cations from themineral substance with selected cations of a known source. For example,in an embodiment, the method 100 comprises bathing an effective amountof the soil substance, the mineral substance or other inorganic materialdirectly in the fertilizer or other agricultural product. When the soilsubstance, mineral substance, or other organic material is bathed infertilizer or other known or desired source of ions, the ions in thesoil substance, mineral substance, or other organic material are exposedor otherwise made readily available for ion exchange with another knownsubstance.

The method 100 shown in FIG. 1B, may further comprise heating themineral substance (zeolite) with a heat source, such that the water heldby the mineral removed at 145 thereby creating a dehydrated mineralsubstance. In an implementation the heat source is an oven. In animplementation the heat source is a heat lamp. This step ensures thatthe zeolite channels are filled with a concentrated fertilizer and/orother agricultural product solution.

The method 100 shown in FIG. 1B may further comprise creating apretreated solution by adding the dehydrated mineral substance to aconcentrated fertilizer and/or other agricultural product solution at147, thus introducing a high concentration of desired ions into thechannels and at the ion exchange sites.

Continuing to refer to FIGS. 1B and 1C, at 150 and 160, respectively,the method 100 may comprise adding the effective amount of thefertilizer and/or other agricultural product into the effective amountof water; and adding the effective amount of the pretreated mineralsolution into the effective amount of the water, thereby creating asolution of the water, the fertilizer and/or other agricultural product,and the mineral substance.

At 170, the method 100 may comprise adding energy into the solution tothereby raise an energy level of known ions in the fertilizer and/orother agricultural product and native ions in the mineral substance,such that the native ions in the mineral substance are exchanged withthe known ions to produce a chemically altered and synthetic zeolite anda homogenous mixture of liquid fertilizer and/or other agriculturalproduct. It will be appreciated that mechanical energy, chemical energy,electromagnetic energy, or other forms of energy may be added to themethod, system or product of the disclosure without departing from thescope of the disclosure. In an implementation, energy may be added intothe method, system or product of the disclosure through high-pressure orthrough a high pressure cyclonic mixing action. In an implementation,energy may be added into the solution by mixing the fertilizer and/orother agricultural product, water and mineral substance using the highpressure cyclonic mixing action.

In an implementation of the method, the method 100 may further compriseproviding an effective amount of ultrapure water sufficient toeffectuate a desired result in a plant and maintain the effective amountof liquid fertilizer and/or other agricultural product and the effectiveamount of the mineral substance in suspension and solution. In animplementation of the method, the method 100 may further compriseproviding an effective amount of double distilled water sufficient toeffectuate a desired result in a plant and maintain the effective amountof liquid fertilizer and/or other agricultural product and the effectiveamount of the mineral substance in suspension and solution. In animplementation of the method, the method 100 may further compriseproviding an effective amount of untreated water sufficient toeffectuate a desired result in a plant and maintain the effective amountof liquid fertilizer and/or other agricultural product and the effectiveamount of the mineral substance in suspension and solution. In animplementation of the method, the method 100 may further compriseproviding an effective amount of potable water sufficient to effectuatea desired result in a plant to a plant and maintain the effective amountof liquid fertilizer and/or other agricultural product and the effectiveamount of the mineral substance in suspension and solution.

In an implementation, a method may add to a 200 gallon mixing tank thefollowing: about 10-20 gallons water; about 1 gallon of liquidfertilizer and/or other agricultural product; and about 100 mL of asolution of mineral substance, which has been processed by being bathedand soaked in ultrapure water. It will be appreciated that such a bathand soak may be for at least 24 hours because the ultrapure water ishydrating the minerals within the mineral substance. It will beappreciated that, in an embodiment, there are about 7 grams of mineralsubstance in the 100 mL solution of the mineral substance. Thereafter,the 200 gallon tank may be filled with water (which may be any type ofwater, such as ultrapure water, double distilled water, untreated water,potable water and the like). There is an ion exchange that occursbetween known ions with ions in the mineral substance. The method addshigh energy mixing such that there is more opportunity for the ions toexchange with each other during the process, such that all or nearly allcations on the mineral particles are exchanged that are available forsuch an exchange.

Referring now to FIG. 2, there is illustrated a method of producing aliquid fertilizer product and/or other agricultural product. In animplementation, the method 200 may comprise providing an effectiveamount of ultrapure water sufficient to effectuate a desired result in aplant at 210. In an implementation, the method 200 may compriseproviding an effective amount of a fertilizer and/or other agriculturalproduct sufficient to effectuate a response in the plant, wherein thefertilizer and/or other agricultural product comprises processedelements at 220. At 230, the method 200 may comprise providing aneffective amount of a mineral substance having a high cation exchangecapacity and comprising a plurality of particles of the mineralsubstance.

In an implementation, the method 200 may further comprise mixing theeffective amount of ultrapure water, the effective amount of thefertilizer and/or other agricultural product and the effective amount ofthe mineral substance together, thereby creating a solution of thewater, the fertilizer and/or other agricultural product and the mineralsubstance at 240. At 250, the method 200 may further comprise addingenergy into the solution to produce a homogenous mixture of a liquidfertilizer product, wherein the liquid fertilizer product and/or otheragricultural product exchanges ions from the mineral substance with theions from the fertilizer and/or other agricultural product, such thatthe ions from the fertilizer and/or other agricultural product aredelivered and carried to a cell where the ions from the fertilizerand/or other agricultural product are absorbed by the plant or arecarried by the plurality of mineral particles directly into the cell.

Referring now to FIG. 3, there is illustrated a synthetic agriculturalproduct. The synthetic agricultural product 300 may comprise aneffective amount of a fertilizer and/or other agricultural product 310sufficient to effectuate a response in a plant. The syntheticagricultural product may comprise an effective amount of a syntheticmineral substance 320 having a high cation exchange capacity. It will beappreciated that the effective amount of the synthetic mineral substance320 may be processed by being bathed in ultrapure water prior to beingincluded as part of the product 300. The effective amount of thesynthetic mineral substance 320 may be further processed such that theresulting synthetic mineral substance 320 comprises mineral particleshaving a particle size within a range of about 1 nanometer to about 1000nanometers or 1 micrometer. An effective amount of water 330 sufficientto effectuate a desired result in a plant and maintain the effectiveamount of the fertilizer and/or other agricultural product and theeffective amount of the synthetic mineral substance in suspension andsolution. It will be appreciated that the effective amount of thefertilizer and/or other agricultural product 310 and the effectiveamount of the synthetic mineral substance 320 may be added into theeffective amount of water 330, thereby creating the syntheticagricultural product 300. Thus, the synthetic agricultural productcomprises the water 330, the fertilizer and/or other agriculturalproduct 310, and the synthetic mineral substance 320. It will beappreciated that prior to being added into the product 300, energy maybe added into the fertilizer and/or other agricultural product 310 andthe mineral substance 320 to thereby raise an energy level of thesolution, such that the native ions in the synthetic mineral substance320 are exchanged with the known ions in the fertilizer and/or otheragricultural product 310 to produce a homogenous mixture of thesynthetic agricultural product 300.

In an implementation, the water 330 of the synthetic agriculturalproduct 300 may be ultrapure water. In an implementation, the syntheticmineral substance 320 is bathed in ultrapure water for at least 24hours. In an implementation, the water 330 of the synthetic agriculturalproduct 300 may be double distilled water. In an implementation, thewater 330 of the synthetic agricultural product 300 may be untreatedwater. In an implementation, the water 330 of the synthetic agriculturalproduct 300 may be potable water.

In an implementation, there are at least two orders of magnitudedifference in volume between the effective amount of the fertilizerand/or other agricultural product 310 and the effective amount of thesynthetic mineral substance 320 when the ratio of mineral particlesolution is 7 g to 100 ml. More generally, the number of ions from thefertilizer and/or other agricultural product should be two to sevenorders of magnitude higher than the number of sites available forexchange in the mineral particles. In an implementation, the syntheticmineral substance 320 has a high cation exchange capacity and has anequivalents in a range of about 10 Milliequivalents/100 g to about 600Milliequivalents/100 g.

In an implementation, the effective amount of water 330 falls within arange of about 0.1 gallon to about 6000 gallons.

In an implementation, the effective amount of the fertilizer and/orother agricultural product 310 is a liquid fertilizer and/or liquidagricultural product or a combination of fertilizer and/or otheragricultural product and other beneficial molecules that promote planthealth and growth. In an implementation, the effective amount of liquidfertilizer and/or other agricultural product falls within a range ofabout 0.10 gallons to about 50 gallons. In an implementation, thefertilizer and/or other agricultural product 310 comprises nanoparticlesof the fertilizer.

In an implementation, the effective amount of the mineral substance 320falls within a range of about 5 grams to about 2 kilograms. In animplementation, the synthetic mineral substance 320 comprises aluminasilicate, silicate, aluminum, or sodium aluminosilicate. In animplementation, the synthetic mineral substance 320 comprisesmontmorillonite, illite, kaolinite, smectite and zeolite. In animplementation, the synthetic mineral substance 320 comprises smectite.In an implementation, the synthetic mineral substance 320 compriseszeolite. In an implementation, the synthetic mineral substance 320 is acarrier of nutrients and other small organic molecules used to protectplants, kill plants, or used as plant growth regulators, such as thoseused to promote plant health, fruiting, growth, or those used to slowplant growth for use by a cell. In an implementation, the syntheticmineral substance 320 comprises both phyllosilicate and tectosilicate.In an implementation, the synthetic mineral substance 320 comprises amineral that has the ability to catalyze or cause or accelerate areaction by acting as a catalyst.

In an implementation, the synthetic agricultural product 300 furthercomprises cations from a known source that have been exchanged with thecations of the synthetic mineral substance 320. In an implementation,the concentration of mineral particles in solution is within a range of1×10⁻⁸ mg/ml to 1×10⁴ mg/ml. The concentration of agricultural productions ranges from 0.01 mg/ml to saturation point.

In an implementation, energy is added into the synthetic agriculturalproduct 300 by mixing the fertilizer and/or other agricultural product310, water 330 and synthetic mineral substance 320 using a vortex,high-pressure, or a high pressure cyclonic mixing action.

Referring to FIG. 4, there is illustrated an example of a syntheticmineral substance 420. It will be appreciated that the mineral substance420 illustrated has been processed by exchanging native ions 422 withions of another substance 424. The synthetic mineral substance 420 maybe clay, zeolite, or other mineral substance, which may be utilized bythe disclosure. In an implementation, the synthetic mineral substance420 may be processed or synthesized by exchanging native ions 422 withknown ions 424 of another substance, such as a fertilizer and/or otheragricultural product, including substances that induce growth of aplant, substances that slow or limit the growth of a plant, orsubstances that kill or are otherwise harmful to a plant.

FIGS. 5 and 6 are diagrams schematically illustrate ion exchangeprocesses 500 and 600, respectively, which result in a synthetic mineralsubstance in accordance with the teachings and principles of thedisclosure. As illustrated in FIG. 5 for example, a mineral substance520 comprises native or naturally occurring ions 522 as noted above. Themineral substance 520 may be processed or synthesized by exchangingnative ions 522 with ions 524 of a known substance, such as a fertilizerand/or other agricultural product. It will be appreciated that the ions524 of the known substance may be introduced to the mineral substance520 through the methods discussed more fully herein. During the process500, the native ions 522 are exchanged with the ions 524 of the knownsubstance until the synthetic mineral substance 520 now has more ions524 of the known substance than native ions 522.

FIG. 6 illustrates the ion exchange process 600, wherein the mineralsubstance 620 is illustrated as a clay material with native ions 622thereon that are available for exchange with ions 624 of a knownsubstance. It will be appreciated that the clay material is shown forillustration purposes only. It will be appreciated that other mineralsubstances 620 may be used besides a clay material for providing an ionexchange between native ions and known ions without departing from thescope of the disclosure. The native ions 622 are illustrated as cationshaving a single positive charge (e.g., Na+), whereas the ions 624 of theknown substance are illustrated as cations having two positive charges(e.g., Ca2+) and anions having a single negative charge (e.g., Cl−),which are shown for illustration purposes only. It will be appreciatedthat there are any number of cations or anions that may be exchangedwithout departing from the scope of the disclosure. The process 600 isillustrated in a time lapse from (a) to (c) for purposes of illustrationand clarity. It will be appreciated that the actual amount of time andthe amount of ions needed for a full process or exchange may bedetermined based on the teachings and principles of the disclosure.

FIG. 7 is a cross-sectional view illustrating an embodiment of asynthetic mineral substance 720 comprising ions 724 from an agriculturalproduct that have been or are in the process of being exchanged withnative ions 722 at exchange sites 723 of the mineral substance 720 inaccordance with the teachings and principles of the disclosure. Thesynthetic mineral substance illustrated also comprises a plurality ofchannels 721, although only a single channel 721 in cross-section isillustrated. It will be appreciated that a high pressure mixing action,such as a vortex, may be used to at least partially fill the pluralityof channels with the known ions 724 and/or other agricultural products.It will be appreciated that ions and molecules can be carried insolution inside the channel 721 without being attached at any time tothe exchange sites 723. As illustrated, there are a plurality ofexchange sites 723 present within the mineral substance 720. The mineralsubstance 720 is illustrated with native ions 722 (illustrated as bothcations and anions, although it will be appreciated that native cations,anions or a combination may be exchanged with ions from a known sourceor substance) that are available for exchange with ions 724 of a knownsubstance, such as ions within an agricultural product. It will beappreciated that there are any number of cations or anions that may beexchanged without departing from the scope of the disclosure. Alsoillustrated are water molecules 726 that are part of the solutioncarried through the channel 721.

EXAMPLES

Example 1 is a method of producing a liquid product. In the method, themethod may comprise providing an effective amount of an agriculturalproduct sufficient to effectuate a desired result in a plant comprisingknown ions; providing an effective amount of a mineral substance havinga high cation exchange capacity; and providing an effective amount ofwater sufficient to effectuate a desired result in a plant and maintainthe effective amount of the agricultural product and the effectiveamount of the mineral substance in suspension and solution.Additionally, the method may comprise forming a solution by adding theeffective amount of the agricultural product and the effective amount ofthe mineral substance into the effective amount of water. The method mayfurther comprise exchanging native ions in the mineral substance withthe known ions in the agricultural product by adding energy into thesolution to thereby raise an energy level of the solution to produce asynthetic mineral substance and a liquid product.

In Example 2, wherein providing an effective amount of water in Example1 comprises providing an effective amount of ultrapure water.

In Example 3, wherein providing an effective amount of water in Example1 comprises providing an effective amount of double distilled water.

In Example 4, wherein providing an effective amount of water in Example1 comprises providing an effective amount of untreated water.

In Example 5, wherein providing an effective amount of water in Example1 comprises providing an effective amount of potable water.

In Example 6, the method of Example 1, wherein there are at least twoorders of magnitude difference between ions in the effective amount ofthe agricultural product and ion exchange sites in the effective amountof the mineral substance.

In Example 7, the mineral substance as in any of Examples 1-6 has a highcation exchange capacity and has an equivalents in a range of about 10Milliequivalents/100 g to about 600 Milliequivalents/100 g.

In Example 8, the effective amount of water as in any of Examples 1-7falls within a range of about 0.1 gallon to about 6000 gallons.

In Example 9, the agricultural product as in any of Examples 1-8 is aliquid fertilizer or a combination of fertilizer and other beneficialmolecules that promote plant health and growth.

In Example 10, the effective amount of liquid fertilizer as in any ofExamples 1-9 falls within a range of about 0.10 gallons to about 50gallons.

In Example 11, the mineral substance as in any of Examples 1-10 fallswithin a range of about 5 micrograms to about 2 kilograms.

In Example 12, the mineral substance as in any of Examples 1-11 has ahigh cation exchange capacity and comprises alumina silicate, silicate,aluminum, sodium aluminosilicate, hydrated sodium calciumaluminosilicate, or other tuff material.

In Example 13, the mineral substance as in any of Examples 1-12comprises montmorillonite, illite, kaolinite, smectite and zeolite.

In Example 14, the mineral substance as in any of Examples 1-13comprises smectite.

In Example 15, the mineral substance as in any of Examples 1-13comprises zeolite.

In Example 16, the mineral substance as in any of Examples 1-15 is acarrier of nutrients and small organic molecules used to protect plants,kill plants, or used as plant growth regulators to promote plant health,fruiting, growth, or used to slow plant growth for use by a cell.

In Example 17, the agricultural product as in any of Examples 1-16comprises particles that fall within a range of 1 nanometer to 1000nanometers.

In Example 18, the mineral substance as in any of Examples 1-13, 16 and17 comprises both phyllosilicate and tectosilicate.

In Example 19, the method as in any of Examples 1-18 further comprisesexchanging ions from the mineral substance with selected ions of a knownsource.

In Example 20, a concentration of mineral particles in solution as inany of Examples 1-19 is within a range of 1×10⁻⁸ mg/ml to 1×10⁴ mg/ml,and wherein a concentration of agricultural product ions or moleculesranges from 0.01 mg/ml to saturation point.

In Example 21, adding energy into the solution as in any of Examples1-20 further comprises mixing the agricultural product, water andmineral substance using a vortex.

In Example 22, the mineral substance as in any of Examples 1-21comprises a plurality of exchange sites where the known ions areexchanged with the native ions in the mineral substance.

In Example 23, the mineral substance as in any of Examples 1-23comprises a plurality of channels, wherein a high pressure mixing actionis used to at least partially fill the plurality of channels with theknown ions and/or other agricultural products.

In Example 24, the liquid product as in any of Examples 1-24 isdelivered to a plant cell and penetrates the plant cell, such that theknown ions contained within the exchange sites of the mineral substanceare released through diffusion and exchanged with the native ions withinthe plant cell, such that there is more efficient use of the known ions.

In Example 25, the mineral substance as in any of Examples 1-24 has aparticle size range from 1 nanometer to 1000 nanometers.

In Example 26, the method as in any of Examples 1-25 further comprisesbathing the effective amount of the mineral substance in a fertilizerand/or an agricultural product.

In Example 27, the method as in any of Examples 1-26 further comprisesbathing the effective amount of the mineral substance in ultrapurewater.

In Example 28, the method as in any of Examples 1-27 further comprisesbathing the effective amount of the mineral substance in ultrapure waterfor at least 24 hours.

Example 29 is a method of producing a liquid product. In the method, themethod may comprise providing an effective amount of ultrapure water toeffectuate a response in a plant; providing an effective amount of anagricultural product sufficient to effectuate a response in the plant;providing an effective amount of a mineral substance having a highcation exchange capacity and comprising a plurality of particles of themineral substance, wherein the mineral substance comprises syntheticnano size particles of mineral elements. The method of Example 29 mayfurther comprise mixing the effective amount of ultrapure water, theeffective amount of the agricultural product and the effective amount ofthe mineral substance together, thereby creating a solution of thewater, the agricultural product and the mineral substance. Further, themethod of Example 29 may comprise adding energy into the solution toproduce a liquid product, wherein the liquid product exchanges nativeions from the mineral substance with known ions from the agriculturalproduct, such that the known ions are delivered and carried to a cellwhere the known ions are absorbed by the plant or are carried by theplurality of mineral particles directly into the cell.

Example 30 is synthetic agricultural product that comprises an effectiveamount of a fertilizer and/or other agricultural product sufficient toeffectuate a desired result in a plant. The synthetic agriculturalproduct of Example 30 may also comprise an effective amount of asynthetic mineral substance having a high cation exchange capacity,wherein the effective amount of the synthetic mineral substancecomprises known ions that have been exchanged with native ions in anative mineral substance thereby creating a synthetic mineral substance.The synthetic agricultural product of Example 30 may further comprise aneffective amount of water sufficient to effectuate a desired result in aplant and maintain the effective amount of the fertilizer and/or otheragricultural products and the effective amount of the synthetic mineralsubstance in suspension and solution. The synthetic agricultural productof Example 30, wherein the effective amount of the fertilizer and/orother agricultural products and the effective amount of the syntheticmineral substance are added into the effective amount of water tothereby create the synthetic agricultural product.

In Example 31, the synthetic mineral substance of Example 30 comprisesparticles having a particle size within a range of about 1 nanometer toabout 1000 nanometers.

In Example 32, the effective amount of water as in any of Examples 30-31is ultrapure water.

In Example 33, the effective amount of water as in any of Examples 30-31the effective amount of water is double distilled water.

In Example 34, the effective amount of water as in any of Examples 30-31the effective amount of water is untreated water.

In Example 35, the effective amount of water as in any of Examples 30-31the effective amount of water is potable water.

In Example 36, there are at least two orders of magnitude differencebetween the effective amount of the fertilizer and/or other agriculturalproducts and the effective amount of the synthetic mineral substance asin any of Examples 30-35.

In Example 37, the synthetic mineral substance as in any of Examples30-36 has a high cation exchange capacity and has an equivalents in arange of about 10 Milliequivalents/100 g to about 600Milliequivalents/100 g.

In Example 38, the effective amount of the synthetic mineral substanceas in any of Examples 30-37 is bathed in ultrapure water for at least 24hours.

In Example 39, the effective amount of water as in any of Examples 30-38falls within a range of about 0.1 gallon to about 6000 gallons. Thesynthetic agricultural product of claim 30, wherein the effective amountof the fertilizer and/or other agricultural products is a liquidfertilizer and/or other agricultural product.

In Example 40, the effective amount of liquid fertilizer and/or otheragricultural products as in any of Examples 30-39 falls within a rangeof about 0.10 gallons to about 50 gallons.

In Example 41, the effective amount of the mineral substance as in anyof Examples 30-40 falls within a range of about 5 grams to about 2kilograms.

In Example 42, the synthetic mineral substance as in any of Examples30-41 comprises alumina silicate, silicate, aluminum, sodiumaluminosilicate or other tuff material.

In Example 43, the synthetic mineral substance as in any of Examples30-42 comprises montmorillonite, illite, kaolinite, smectite andzeolite.

In Example 44, the synthetic mineral substance as in any of Examples30-43 comprises smectite.

In Example 45, the synthetic mineral substance as in any of Examples30-43 comprises zeolite.

In Example 46, the synthetic mineral substance as in any of Examples30-45 is a carrier of nutrients and other small organic molecules usedto protect plants, kill plants, or used as plant growth regulators topromote plant health, fruiting, growth, or used to slow plant growth foruse by a cell.

In Example 47, the fertilizer and/or other agricultural product as inany of Examples 30-46 comprises particles that fall within a range of 1nanometer to 1000 nanometers.

In Example 48, the synthetic mineral substance as in any of Examples30-43 comprises both phyllosilicate and tectosilicate.

In Example 49, the agricultural product as in any of Examples 30-48further comprises cations from a known source that have been exchangedwith the cations of the synthetic mineral substance.

In Example 50, energy is added into the synthetic product as in any ofExamples 30-49 by mixing the fertilizer and/or other agriculturalproduct, water and synthetic mineral substance using a vortex.

In Example 51, the synthetic mineral substance as in any of Examples30-50 comprises a plurality of exchange sites where the known ions areexchanged with the native ions of the native mineral substance.

In Example 52, the synthetic mineral substance as in any of Examples30-51 comprises a plurality of channels, wherein the plurality ofchannels are at least partially filled with the known ions by a highpressure mixing action.

In Example 53, the synthetic agricultural product as in any of Examples30-52 is delivered to a plant cell and penetrates the plant cell, suchthat the known ions contained within the exchange sites of the syntheticmineral substance are released through diffusion and exchanged with thenative ions within the plant cell, such that there is more efficient useof the known ions.

In Example 54, the synthetic mineral substance as in any of Examples30-53 has a particle size range from 1 nanometer to 1000 nanometers.

In Example 55, the synthetic mineral substance as in any of Examples30-54 has been bathed in fertilizer and/or other agricultural product.

In the foregoing Detailed Description of the Disclosure, variousfeatures of the disclosure are grouped together in a singleimplementation or embodiment for the purpose of streamlining thedisclosure. This method of disclosure is not to be interpreted asreflecting an intention that the claimed disclosure requires morefeatures than are expressly recited in each claim. Rather, as thefollowing embodiments reflect, inventive aspects lie in less than allfeatures of a single foregoing disclosed embodiment. Thus, the followingembodiments are hereby incorporated into this Detailed Description ofthe Disclosure by this reference, with each embodiment standing on itsown as a separate embodiment of the disclosure.

It is to be understood that the above-described arrangements are onlyillustrative of the application of the principles of the disclosure.Numerous modifications and alternative arrangements may be devised bythose skilled in the art without departing from the spirit and scope ofthe disclosure and the appended claims are intended to cover suchmodifications and arrangements. Thus, while the disclosure has beenshown in the drawings and described above with particularity and detail,it will be apparent to those of ordinary skill in the art that numerousmodifications, including, but not limited to, variations in size,materials, shape, form, ratios of elements or molecules, function andmanner of operation, assembly and use may be made without departing fromthe principles and concepts set forth herein.

What is claimed is:
 1. A synthetic agricultural product comprising: afertilizer and/or other agricultural product comprising a number ofknown ions available to be exchanged, wherein the known ions do notinclude ammonium; a mineral substance comprising a number of native ionexchange sites; and an effective amount of water for maintaining thefertilizer and/or other agricultural product and the mineral substancein a suspension or solution; wherein at least one of the known ionsavailable to be exchanged may attach to at least one of the native ionexchange sites; and wherein a volume of the fertilizer and/or otheragricultural product and a volume of the mineral substance are such thatthe number of known ions available to be exchanged is at least twoorders of magnitude greater than the number of native ion exchangesites.
 2. The synthetic agricultural product of claim 1, wherein themineral substance comprises particles having a particle size within arange of about 1 nanometer to about 1000 nanometers.
 3. The syntheticagricultural product of claim 1, wherein the effective amount of wateris ultrapure water.
 4. The synthetic agricultural product of claim 1,wherein the effective amount of water is double distilled water.
 5. Thesynthetic agricultural product of claim 1, wherein the effective amountof water is untreated water.
 6. The synthetic agricultural product ofclaim 1, wherein the effective amount of water is potable water.
 7. Thesynthetic agricultural product of claim 1, wherein the mineral substancehas a high cation exchange capacity and has an equivalents in a range ofabout 10 Milliequivalents/100 g to about 600 Milliequivalents/100 g. 8.The synthetic agricultural product of claim 1, wherein the effectiveamount of the mineral substance is bathed in ultrapure water for atleast 24 hours.
 9. The synthetic agricultural product of claim 1,wherein the effective amount of water falls within a range of about 0.1gallon to about 6000 gallons.
 10. The synthetic agricultural product ofclaim 1, wherein the fertilizer and/or other agricultural product is aliquid fertilizer and/or other agricultural product.
 11. The syntheticagricultural product of claim 10, wherein the liquid fertilizer and/orother agricultural product falls within a range of about 0.10 gallons toabout 50 gallons.
 12. The synthetic agricultural product of claim 11,wherein the mineral substance falls within a range of about 5 grams toabout 2 kilograms.
 13. The synthetic agricultural product of claim 1,wherein the mineral substance comprises alumina silicate, silicate,aluminum, sodium aluminosilicate or other tuff material.
 14. Thesynthetic agricultural product of claim 1, wherein the mineral substancecomprises montmorillonite, illite, kaolinite, smectite and zeolite. 15.The synthetic agricultural product of claim 1, wherein the mineralsubstance comprises smectite.
 16. The synthetic agricultural product ofclaim 1, wherein the mineral substance comprises zeolite.
 17. Thesynthetic agricultural product of claim 1, wherein the mineral substanceis a carrier of nutrients and other small organic molecules used toprotect plants, kill plants, or used as plant growth regulators topromote plant health, fruiting, growth, or used to slow plant growth foruse by a cell.
 18. The synthetic agricultural product of claim 1,wherein the fertilizer and/or other agricultural product comprisesparticles that fall within a range of 1 nanometer to 1000 nanometers.19. The synthetic agricultural product of claim 1, wherein the mineralsubstance comprises both phyllosilicate and tectosilicate.
 20. Thesynthetic agricultural product of claim 1, wherein the agriculturalproduct further comprises cations from a known source that have beenexchanged with the cations of the mineral substance.
 21. The syntheticagricultural product of claim 1, wherein energy is added into thesynthetic product by mixing the fertilizer and/or other agriculturalproduct, water, and mineral substance using a vortex.
 22. The syntheticagricultural product of claim 1, wherein the mineral substance comprisesnative ions having a high cation exchange capacity, and wherein theknown ions of the fertilizer and/or other agricultural product areconfigured to be exchanged with the native ions of the mineralsubstance.
 23. The synthetic agricultural product of claim 22, whereinthe mineral substance comprises a plurality of channels, wherein theplurality of channels are at least partially filled with the known ionsby a high pressure mixing action.
 24. The synthetic agricultural productof claim 23, wherein the synthetic agricultural product is delivered toa plant cell and penetrates the plant cell, such that the known ionscontained within the native ion exchange sites of the mineral substanceare released through diffusion and exchanged with the native ions withinthe plant cell, such that there is more efficient use of the known ionsof the fertilizer and/or other agricultural product.
 25. The syntheticagricultural product of claim 1, wherein the mineral substance has beenbathed in fertilizer and/or other agricultural product.